Department spokeswoman Liz Hill said in a statement Wednesday that DeVos' one-year salary of $199,700 will be divided evenly among the four organizations.
One of the groups, Dreams Soar, works to encourage girls to pursue careers in the fields of science, engineering and mathematics. Another, Kids Hope USA, helps at-risk children. Vision to Learn provides eyeglasses to low-income children and Special Olympics helps children and adults with disabilities.
DeVos is married to Dick DeVos, the heir to the Amway marketing fortune. She travels around the country on her own private plane and foots the bill.
Copyright 2018 The Associated Press. All rights reserved. This material may not be published, broadcast, rewritten or redistributed.